Nielsen & Chuang · Chapter 2, Introduction to quantum mechanics · p. 101
Theorem2.5 - The positive operators of unit trace are exactly the mixtures of pure states
Every density operator comes from an ensemble.
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The Theorem
A system is prepared in one of the pure states, in the state with probability .It is then described by the density operator of the ensemble,(1)✦Theorem 2.5 says which operators arise in this way: an operator is the density operator of some ensemble if and only if it has trace one and is positive.✦
A Quantum System
A quantum system is described by its state space , a finite dimensional complex Hilbert space.✦ A pure state of is a unit vector of ,; it determines the operator on , the rank one projector onto .A state of , pure or mixed, is a positive operator of unit trace on :(2)✦
An ensemble of pure states of is a finite family of pure states of with probabilities that are nonnegative and sum to one.✦The density operator of an ensemble of pure states of is the operator on .✦
The Claim
Theorem 1. Let be a quantum system. Every state of arises from an ensemble: for an operator on ,(3)✦ More precisely, for an operator on ,(4)✦
What Is Checked
The claim is stated over the states of a quantum system with a finite dimensional state space and over the ensembles of pure states of , each with its density operator(1).
The library proves that both constructions give states of : the projector onto a unit vector is positive with unit trace, and so is , a sum of such projectors with nonnegative weights that sum to one.