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Nielsen & Chuang · Chapter 2, Introduction to quantum mechanics · p. 76

Exercise 2.39 - An explicit basis of the d×dd \times d matrices, Hermitian and orthonormal for the Hilbert-Schmidt inner product

The Gell-Mann matrices form an orthonormal Hermitian basis.

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The Exercise

The operators on the state space of a dd-level system form a vector space of their own. In a fixed orthonormal basis |1⟩,…,|d⟩|1\rangle, \dots, |d\rangle of the system they are the complex d×dd \times d matrices; we write Md(ℂ)M_d(\mathbb{C}) for this space, which has dimension d2d^2. The Hilbert-Schmidt inner product of two d×dd \times d matrices AA and BB is the trace of A†BA^\dagger B: (A,B)=tr⁡(A†B).(A, B) = \operatorname{tr}\bigl(A^\dagger B\bigr).(1)✦

The exercise asks for an orthonormal basis of Md(ℂ)M_d(\mathbb{C}) for this inner product whose elements are all Hermitian, each of them an observable of the system.

The Gell-mann Basis

The library answers with an explicit family of d2d^2 matrices, one for each ordered pair of indices, built from the matrix units. The matrix unit Ejk=|j⟩⟨k|E_{jk} = |j\rangle\langle k| is the d×dd \times d matrix with a 11 in row jj and column kk and zeros elsewhere.

The generalised Gell-Mann matrix GjkG_{jk} of an ordered pair (j,k)(j, k) of indices in {1,…,d}\{1, \dots, d\} is the complex d×dd \times d matrix Gjk={12(Ejk+Ekj),j<k,i2(Ekj−Ejk),j>k,Ejj,j=k.G_{jk} = \begin{cases} \dfrac{1}{\sqrt 2}\,\bigl(E_{jk} + E_{kj}\bigr), & j < k,\\[8pt] \dfrac{i}{\sqrt 2}\,\bigl(E_{kj} - E_{jk}\bigr), & j > k,\\[8pt] E_{jj}, & j = k. \end{cases}(2)✦

The Gell-Mann basis 𝒢\mathcal{G} of Md(ℂ)M_d(\mathbb{C}) is the basis whose elements are the d2d^2 matrices GjkG_{jk}: every complex d×dd \times d matrix AA has a unique expansion A=∑j,k=1dcjkGjk,cjk∈ℂ.A = \sum_{j,k=1}^{d} c_{jk}\, G_{jk}, \qquad c_{jk} \in \mathbb{C}.(3)✦

The Claim

Theorem 1. For any number dd of levels, the elements of the Gell-Mann basis 𝒢\mathcal{G} of Md(ℂ)M_d(\mathbb{C}) are Hermitian: for all indices jj and kk, Gjk†=Gjk.G_{jk}^\dagger = G_{jk}.(4)✦ They are orthonormal for the Hilbert-Schmidt inner product: for all ordered pairs (j,k)(j, k) and (l,m)(l, m) of indices, (Gjk,Glm)=δjlδkm.(G_{jk}, G_{lm}) = \delta_{jl}\,\delta_{km}.(5)✦

What Is Checked

The claim is stated over the Gell-Mann basis 𝒢\mathcal{G} of (3), whose elements are the matrices (2), and over the Hilbert-Schmidt inner product (1), for a system of any finite number dd of levels.

About these constructions the library proves that the d2d^2 generalised Gell-Mann matrices GjkG_{jk} are linearly independent over ℂ\mathbb{C}.✦